Surface Science and Electrochemical Model Studies on the Interaction of Graphite and Li-Containing Ionic Liquids.

ABSTRACT: The process of solid-electrolyte interphase (SEI) formation is systematically investigated along with its chemical composition on carbon electrodes in an ionic liquid-based, Li-containing electrolyte in a combined surface science and electrochemical model study using highly oriented pyrolytic graphite (HOPG) and binder-free graphite powder electrodes (Mage) as model systems. The chemical decomposition process is explored by deposition of Li on a pre-deposited multilayer film of 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([BMP][TFSI]) under ultrahigh vacuum conditions. Electrochemical SEI formation is induced by and monitored during potential cycling in [BMP][TFSI]+0.1 m LiTFSI. The chemical composition of the resulting layers is characterized by X-ray photoelectron spe

SUBMITTER: Weber I 

PROVIDER: S-EPMC7317785 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature