Bond-length distributions for ions bonded to oxygen: results for the transition metals and quantification of the factors underlying bond-length variation in inorganic solids.
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ABSTRACT:
SUBMITTER: Gagne OC
PROVIDER: S-EPMC7340253 | biostudies-literature | 2020 Jul
REPOSITORIES: biostudies-literature
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Bond-length distributions for ions bonded to oxygen: results for the transition metals and quantification of the factors underlying bond-length variation in inorganic solids.
Gagné Olivier Charles OC Hawthorne Frank Christopher FC
IUCrJ 20200609 Pt 4
Bond-length distributions are examined for 63 transition metal ions bonded to O<sup>2-</sup> in 147 configurations, for 7522 coordination polyhedra and 41 488 bond distances, providing baseline statistical knowledge of bond lengths for transition metals bonded to O<sup>2-</sup>. <i>A priori</i> bond valences are calculated for 140 crystal structures containing 266 coordination polyhedra for 85 transition metal ion configurations with anomalous bond-length distributions. Two new indices, Δ<sub>to ...[more]
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