Bond-breaking induced Lifshitz transition in robust Dirac semimetal VAI₃.

ABSTRACT: Topological electrons in semimetals are usually vulnerable to chemical doping and environment change, which restricts their potential application in future electronic devices. In this paper, we report that the type-II Dirac semimetal [Formula: see text] hosts exceptional, robust topological electrons which can tolerate extreme change of chemical composition. The Dirac electrons remain intact, even after a substantial part of V atoms have been replaced in the [Formula: see text] solid solutions. This Dirac semimetal state ends at [Formula: see text], where a Lifshitz transition to p-type trivial metal occurs. The V-Al bond is completely broken in this transition as long as the bonding orbitals are fully depopulated by the holes donated from Ti substitution. In other words, the Dirac electro

SUBMITTER: Liu Y 

PROVIDER: S-EPMC7355027 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature