Lithium lanthanum titanate perovskite as an anode for lithium ion batteries.

ABSTRACT: Conventional lithium-ion batteries embrace graphite anodes which operate at potential as low as metallic lithium, subjected to poor rate capability and safety issues. Among possible alternatives, oxides based on titanium redox couple, such as spinel Li₄Ti₅O₁₂, have received renewed attention. Here we further expand the horizon to include a perovskite structured titanate La_0.5Li_0.5TiO₃ into this promising family of anode materials. With average potential of around 1.0 V vs. Li⁺/Li, this anode exhibits high specific capacity of 225 mA h g^-1 and sustains 3000 cycles involving a reversible phase transition. Without decrease the particle size from micro to nano scale, its rate performance has exceeded the na

SUBMITTER: Zhang L 

PROVIDER: S-EPMC7359355 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature