Comparison between Benzothiadizole-Thiophene- and Benzothiadizole-Furan-Based D-A-π-A Dyes Applied in Dye-Sensitized Solar Cells: Experimental and Theoretical Insights.

ABSTRACT: Three novel donor-acceptor-π-acceptor-type compounds (WS5, WS6, and WS7) were synthesized and investigated in dye-sensitized solar cells (DSSCs) exploring the effect of conjugated linkers on device performance. The new dyes showed strong light-harvesting ability in the visible region with relatively high molar absorption coefficients (>21 800 M^-1 cm^-1). This can be attributed to their intrinsic charge transfer (CT) from the arylamine to the acceptor group. Density functional theory (DFT) calculations revealed a favorable lowest unoccupied molecular orbital (LUMO) energy level, allowing efficient injection into the semiconductor conduction band after excitation. Upon application in DSSC devices, the WS5 dye containing 4,7-di(furan-2-yl)benzo[c][1,2,5]thiadiazole

SUBMITTER: Sharmoukh W 

PROVIDER: S-EPMC7364726 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature