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Fast Crystallization-Deposition of Orderly Molecule Level Heterojunction Thin Films Showing Tunable Up-Conversion and Ultrahigh Photoelectric Response.


ABSTRACT: Molecular cocrystals have received much attention for tuning physicochemical properties in pharmaceutics, luminescence, organic electronics, and so on. However, the effective methods for the formation of orderly cocrystal thin films are still rather limited, which have largely restricted their photofunctional and optoelectronic applications. In this work, a fast crystallization-deposition procedure is put forward to obtain acridine (AD)-based cocrystals, which are self-assembled with three typical isophthalic acid derivatives (IPA, IPB, and TMA). The obtained donor-acceptor cocrystal complexes exhibit an adjustable energy level, wide range of photoluminescence color, and rotational angle-dependent polarized emission. The orderly and uniform cocrystal thin films further present tunable one-

SUBMITTER: Yang XG 

PROVIDER: S-EPMC7379383 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature