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Silver(I) Complexes of Two Flexible Bis-phospholane Ligands: Metallamacrocycles, Polymeric Chains, and Metallacryptands.

ABSTRACT: In a 2:2 reaction with silver(I) chloride or bromide, 1,5-bis(1-phospholano)pentane (1a) afforded frame-like macrocyclic structures, with intra- (2, Cl) or intermolecular (3, Br) halido bridges. In contrast, 1,7-bis(1-phospholano)heptane (1b) formed coordination polymers 4a (Cl) and 4b (Br) with bridging bis-phospholane and halido ligands. A unique paddle wheel-type metallacryptand structure 5 was obtained from 1a and silver(I) bromide in a 2:3 reaction (M:L). All complexes were fully characterized by NMR, IR spectroscopy, mass spectrometry, and X-ray crystallography.

SUBMITTER: Boar P

PROVIDER: S-EPMC7386914 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature

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Silver(I) Complexes of Two Flexible Bis-phospholane Ligands: Metallamacrocycles, Polymeric Chains, and Metallacryptands.

Boar Paul P Lönnecke Peter P Hey-Hawkins Evamarie E

Zeitschrift fur anorganische und allgemeine Chemie 20200512 13

In a 2:2 reaction with silver(I) chloride or bromide, 1,5-bis(1-phospholano)pentane (1a) afforded frame-like macrocyclic structures, with intra- (2, Cl) or intermolecular (3, Br) halido bridges. In contrast, 1,7-bis(1-phospholano)heptane (1b) formed coordination polymers 4a (Cl) and 4b (Br) with bridging bis-phospholane and halido ligands. A unique paddle wheel-type metallacryptand structure 5 was obtained from 1a and silver(I) bromide in a ...[more]

PMID: 32742042

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