Iron-Gallium and Cobalt-Gallium Tetraphosphido Complexes.

ABSTRACT: The synthesis and characterization of two heterobimetallic complexes [K([18]crown-6){(η⁴-C₁₄H₁₀)Fe(μ-η⁴:η²-P₄)Ga(nacnac)}] (1) (C₁₄H₁₀ = anthracene) and [K(dme)₂{(η⁴-C₁₄H₁₀)Co(μ-η⁴:η²-P₄)Ga(nacnac)}] (2) with strongly reduced P₄ units is reported. Compounds 1 and 2 are prepared by reaction of the gallium(III) complex [(nacnac)Ga(η²-P₄)] (nacnac = CH[CMeN(2,6-iPr₂C₆H₃)]₂) with bis(anthracene)ferrate(1-) and -cobaltate(1-) salts. The molecular structures of 1 and 2 were determined by X-ray crystallography

SUBMITTER: Ziegler CGP 

PROVIDER: S-EPMC7386938 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature