Ontology highlight
ABSTRACT:
SUBMITTER: Tu ZL
PROVIDER: S-EPMC7404162 | biostudies-literature | 2020 Aug
REPOSITORIES: biostudies-literature
Tu Zhen-Long ZL Yan Zhi-Ping ZP Liang Xiao X Chen Lei L Wu Zheng-Guang ZG Wang Yi Y Zheng You-Xuan YX Zuo Jing-Lin JL Pan Yi Y
Advanced science (Weinheim, Baden-Wurttemberg, Germany) 20200614 15
To boost intrinsic circularly polarized luminescence (CPL) properties of chiral emitters, an axially chiral biphenyl unit is inlaid in thermally activated delayed fluorescent (TADF) skeleton, urging the participation of chiral source in frontier molecular orbital distributions. A pair of enantiomers, (<i>R</i>)-BPPOACZ and (<i>S</i>)-BPPOACZ, containing the cyano as electron-withdrawing moieties and carbazole and phenoxazine as electron-donating units are synthesized and separated. The circularl ...[more]