Di-aqua-bis-{μ-1,5-bis-[(pyridin-2-yl)methyl-idene]carbonohydrazide(1-)}di-μ-chlorido-tetra-chlorido-tetra-zinc(II).

ABSTRACT: A tetra-nuclear Zn^II complex, [Zn₄(C₁₃H₁₁N₆O)₂Cl₆(H₂O)₂] or {[Zn₂(HL)(H₂O)(Cl₂)](μCl)₂[Zn₂(HL)(H₂O)(Cl)]}₂, was synthesized by mixing an equimolar amount of a methanol solution containing ZnCl₂ and a methanol solution containing the ligand H₂ L [1,5-bis-(pyridin-2-yl-methyl-ene)carbono-hydrazide]. In the tetra-nuclear complex, each of the two ligand mol-ecules forms a dinuclear unit that is connected to another dinuclear unit by two bridging chloride anions. In each dinuclear unit, one Zn^II cation is penta-coordinated in a N₂OCl₂ in a distorted square-pyra

SUBMITTER: Seck TM 

PROVIDER: S-EPMC7405581 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature