Structural diversity in copper(I) iodide complexes with 6-thioxopiperidin-2-one, piperidine-2,6-di-thione and isoindoline-1,3-di-thione ligands.

ABSTRACT: Copper(I) iodide complexes are well known for displaying a diverse array of structural features even when only small changes in ligand design are made. This structural diversity is well displayed by five copper(I) iodide compounds reported here with closely related piperidine-2,6-di-thione (SNS), isoindoline-1,3-di-thione (SNS6), and 6-thioxopiperidin-2-one (SNO) ligands: di-μ-iodido-bis-[(aceto-nitrile-κN)(6-sulfanylidenepiperidin-2-one-κS)copper(I)], [Cu₂I₂(CH₃CN)₂(C₅H₇NOS)₂] (I), bis-(aceto-nitrile-κN)tetra-μ₃-iodido-bis-(6-sulfanylidenepiperidin-2-one-κS)-tetra-hedro-tetra-copper(I), [Cu₄I₄(CH₃CN)₄(C₅H

SUBMITTER: Wheaton AM 

PROVIDER: S-EPMC7405592 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature