Synthesis of ZnO Nanoparticles Doped with Cobalt Using Bimetallic ZIFs as Sacrificial Agents.

ABSTRACT: : We report here a simple two-stage synthesis of zinc-cobalt oxide nanoparticles. We used Zn/Co-zeolite imidazolate framework (ZIF)-8 materials as precursors for annealing and optional impregnation with a silicon source for the formation of a protective layer on the surface of oxide nanoparticles. Using bimetallic ZIFs allowed us to trace the phase transition of the obtained oxide nanoparticles from wurtzite ZnO to spinel Co₃O₄ structures. Using (X-Ray diffraction) XRD and (X-ray Absorption Near Edge Structure) XANES techniques, we confirmed the incorporation of cobalt ions into the ZnO structure up to 5 mol.% of Co. Simple annealing of Zn/Co-ZIF-8 materials in the air led to the formation of oxide nanoparticles of about 20-30 nm, while additional treatment of

SUBMITTER: Butova VV 

PROVIDER: S-EPMC7408057 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature