PH-Responsive Properties of Asymmetric Nanopapers of Nanofibrillated Cellulose.

ABSTRACT: Inspired by plant movements driven by the arrangement of cellulose, we have fabricated nanopapers of nanofibrillated cellulose (NFC) showing actuation under pH changes. Bending was achieved by a concentration gradient of charged groups along the film thickness. Hence, the resulting nanopapers contained higher concentration of charged groups on one side of the film than on the opposite side, so that pH changes resulted in charge-dependent asymmetric deprotonation of the two layers. Electrostatic repulsions separate the nanofibers in the nanopaper, thus facilitating an asymmetric swelling and the subsequent expanding that results in bending. Nanofibrillated cellulose was modified by 2,2,6,6-tetramethylpiperidin-1-yl)oxyl radical (TEMPO) oxidation at two reaction times to get different surfac

SUBMITTER: Chemin M 

PROVIDER: S-EPMC7408521 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature