Diastereoselective peroxidation of derivatives of Baylis-Hillman adducts.

ABSTRACT: Cyclic derivatives of Baylis-Hillman adducts were synthesized. Cobalt-catalyzed peroxidation of these cyclic lactones afforded silyl peroxides in diastereomeric ratios ranging from 91:9 to 97:3.

SUBMITTER: Zuckerman DS 

PROVIDER: S-EPMC7437930 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature