Preparation of a Hydrogel-Based Adsorbent for Metal Ions through High Internal Phase Emulsion Polymerization.

ABSTRACT: In this work, a porous hydrogel-based adsorbent for metal ions was prepared through the copolymerization of acrylic acid and 2-hydroxyethyl methacrylate using a high internal phase emulsion (HIPE) method. Stretched molecular chains in the hydrogel ensure the excellent accessibility of functional sites by the metal ions. A highly open cellular structure endows the P(AANa-co-HEMA) gel with high transport rates as a promising adsorbent. Adsorption properties were investigated by three isotherm models and two kinetic models. X-ray photoelectron spectroscopy analysis proved a chelating interaction between -COO^- and metal ions. The adsorption capacity reached 630 mg·g^-1 for Pb²⁺ under 303 K and a 400 μg·mL^-1 initial concentration. The results sh

SUBMITTER: Chen J 

PROVIDER: S-EPMC7439275 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature