Accessing new magnetic regimes by tuning the ligand spin-orbit coupling in van der Waals magnets.

ABSTRACT: Van der Waals (VdW) materials have opened new directions in the study of low dimensional magnetism. A largely unexplored arena is the intrinsic tuning of VdW magnets toward new ground states. Chromium trihalides provided the first such example with a change of interlayer magnetic coupling emerging upon exfoliation. Here, we take a different approach to engineer previously unknown ground states, not by exfoliation, but by tuning the spin-orbit coupling (SOC) of the nonmagnetic ligand atoms (Cl, Br, I). We synthesize a three-halide series, CrCl_{3 - x - y} Br _x I _y , and map their magnetic properties as a function of Cl, Br, and I content. The resulting triangular phase diagrams unveil a frustrated regime near CrCl₃. First-

SUBMITTER: Tartaglia TA 

PROVIDER: S-EPMC7439302 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature