Anthraquinone-Mediated Fuel Cell Anode with an Off-Electrode Heterogeneous Catalyst Accessing High Power Density when Paired with a Mediated Cathode.

ABSTRACT: The development of processes for electrochemical energy conversion and chemical production could benefit from new strategies to interface chemical redox reactions with electrodes. Here, we employ a diffusible low-potential organic redox mediator, 9,10-anthraquinone-2,7-disulfonic acid (AQDS), to promote efficient electrochemical oxidation of H₂ at an off-electrode heterogeneous catalyst. This unique approach to integrate chemical and electrochemical redox processes accesses power densities up to 228 mW/cm² (528 mW/cm² with iR-correction). These values are significantly higher than those observed in previous mediated electrochemical H₂ oxidation methods, including those using enzymes or inorganic mediators. The approach described herein shows how

SUBMITTER: Preger Y 

PROVIDER: S-EPMC7447196 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature