Improving Fatigue Resistance of Dihydropyrene by Encapsulation within a Coordination Cage.

ABSTRACT: Photochromic molecules undergo reversible isomerization upon irradiation with light at different wavelengths, a process that can alter their physical and chemical properties. For instance, dihydropyrene (DHP) is a deep-colored compound that isomerizes to light-brown cyclophanediene (CPD) upon irradiation with visible light. CPD can then isomerize back to DHP upon irradiation with UV light or thermally in the dark. Conversion between DHP and CPD is thought to proceed via a biradical intermediate; bimolecular events involving this unstable intermediate thus result in rapid decomposition and poor cycling performance. Here, we show that the reversible isomerization of DHP can be stabilized upon confinement within a Pd^II₆L₄ coordination cage. By protecting this

SUBMITTER: Canton M 

PROVIDER: S-EPMC7453400 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature