Site-dependent reactivity of MoS₂ nanoparticles in hydrodesulfurization of thiophene.

ABSTRACT: The catalytically active site for the removal of S from organosulfur compounds in catalytic hydrodesulfurization has been attributed to a generic site at an S-vacancy on the edge of MoS₂ particles. However, steric constraints in adsorption and variations in S-coordination means that not all S-vacancy sites should be considered equally active. Here, we use a combination of atom-resolved scanning probe microscopy and density functional theory to reveal how the generation of S-vacancies within MoS₂ nanoparticles and the subsequent adsorption of thiophene (C₄H₄S) depends strongly on the location on the edge of MoS₂. Thiophene adsorbs directly at open corner vacancy sites, however, we find that its adsorption at S-vacancy sites away from the MoS₂ particle corners leads to an activated and concerted displacement of neighboring edge S. This mechanism allows the reactant to self-generate a double CUS site that reduces steric effects in more constrained sites along the edge.

SUBMITTER: Salazar N 

PROVIDER: S-EPMC7459117 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature