An Expandable Hydrogen-Bonded Organic Framework Characterized by Three-Dimensional Electron Diffraction.

ABSTRACT: A molecular crystal of a 2-D hydrogen-bonded organic framework (HOF) undergoes an unusual structural transformation after solvent removal from the crystal pores during activation. The conformationally flexible host molecule, ABTPA, adapts its molecular conformation during activation to initiate a framework expansion. The microcrystalline activated phase was characterized by three-dimensional electron diffraction (3D ED), which revealed that ABTPA uses out-of-plane anthracene units as adaptive structural anchors. These units change orientation to generate an expanded, lower density framework material in the activated structure. The porous HOF, ABTPA-2, has robust dynamic porosity (SA_BET = 1183 m² g^-1) and exhibits negative area thermal e

SUBMITTER: Cui P 

PROVIDER: S-EPMC7467715 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature