Formation of a nona-nuclear copper(II) cluster with 3,5-di-methyl-pyrazolate starting from an NHC complex of copper(I) chloride.

ABSTRACT: The complete nona-nuclear cluster in bis-[1,3-bis-(2,6-di-methyl-phen-yl)imid-azol-ium] di-μ-chlorido-tetra-chlorido-octa-kis-(μ-3,5-di-methyl-pyrazolato)hexa-μ₃-hydroxido-nona-copper(II) chloro-form disolvate, [HIXy]₂[Cu₉(μ-pz*)₈(μ₃-OH)₆(μ₂-Cl)₂Cl₄]·2CHCl₃ or (C₁₉H₂₁N₂)₂[Cu₉(C₅H₇N₂)₈Cl₆(OH)₆]·2CHCl₃, where pz* is the 3,5-di-methyl-pyrazolyl anion, C₅H₇N₂ ^-, and HIXy is the 1,3-bis-(2,6-di-methyl-phen-yl)imidazolium cation, C₁₉H₂₁N₂ ⁺, is generated by a crystallogra

SUBMITTER: Dodds CA 

PROVIDER: S-EPMC7472752 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature