Growth of a self-assembled monolayer decoupled from the substrate: nucleation on-command using buffer layers.

ABSTRACT: Structural polymorphism is ubiquitous in physisorbed self-assembled monolayers formed at the solution-solid interface. One of the ways to influence network formation at this interface is to physically decouple the self-assembled monolayer from the underlying substrate thereby removing the influence of the substrate lattice, if any. Here we show a systematic exploration of self-assembly of a typical building block, namely 4-tetradecyloxybenzoic acid at the 1-phenyloctane-graphite interface in the presence and in the absence of a buffer layer formed by a long chain alkane, namely n-pentacontane. Using scanning tunneling microscopy (STM), three different structural polymorphs were identified for 4-tetradecyloxybenzoic acid at the 1-phenyloctane-graphite interface. Surprisingly, the sam

SUBMITTER: Reynaerts R 

PROVIDER: S-EPMC7476593 | biostudies-literature | 2020

REPOSITORIES: biostudies-literature