Two-dimensional, conductive niobium and molybdenum metal-organic frameworks.

ABSTRACT: The incorporation of second-row transition metals into metal-organic frameworks could greatly improve the performance of these materials across a wide variety of applications due to the enhanced covalency, redox activity, and spin-orbit coupling of late-row metals relative to their first-row analogues. Thus far, however, the synthesis of such materials has been limited to a small number of metals and structural motifs. Here, we report the syntheses of the two-dimensional metal-organic framework materials (H₂NMe₂)₂Nb₂(Cl₂dhbq)₃ and Mo₂(Cl₂dhbq)₃ (H₂Cl₂dhbq = 3,6-dichloro-2,5-dihydroxybenzoquinone), which feature mononuclear niobium or molybdenum metal nodes and are formed

SUBMITTER: Ziebel ME 

PROVIDER: S-EPMC7481840 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature