¹³C isotope enrichment of the central trityl carbon decreases fluid solution electron spin relaxation times.

ABSTRACT: Electron spin relaxation times for perdeuterated Finland trityl 99% enriched in ¹³C at the central carbon (¹³C₁-dFT) were measured in phosphate buffered saline (pH = 7.2) (PBS) solution at X-band. The anisotropic ¹³C₁ hyperfine (A_x = A_y = 18 ± 2, A_z = 162 ± 1 MHz) and g values (2.0033, 2.0032, 2.00275) in a 9:1 trehalose:sucrose glass at 293 K and in 1:1 PBS:glycerol at 160 K were determined by simulation of spectra at X-band and Q-band. In PBS at room temperature the tumbling correlation time, τ_R, is 0.29 ± 0.02 ns. The linewidths are broadened by incomplete motional averaging of the hyperfine anisotropy and T₂ is 0.13 ± 0.02 µs, which is shorter than the T₂ ~ 3.8 µs fo

SUBMITTER: Moore W 

PROVIDER: S-EPMC7492462 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature