Wide range zero-thermal-quenching ultralong phosphorescence from zero-dimensional metal halide hybrids.

ABSTRACT: Materials with ultralong phosphorescence have wide-ranging application prospects in biological imaging, light-emitting devices, and anti-counterfeiting. Usually, molecular phosphorescence is significantly quenched with increasing temperature, rendering it difficult to achieve high-efficiency and ultralong room temperature phosphorescence. Herein, we spearhead this challenging effort to design thermal-quenching resistant phosphorescent materials based on an effective intermediate energy buffer and energy transfer route. Co-crystallized assembly of zero-dimensional metal halide organic-inorganic hybrids enables ultralong room temperature phosphorescence of (Ph₄P)₂Cd₂Br₆ that maintains luminescent stability across a wide temperature range from 100 t

SUBMITTER: Liu S 

PROVIDER: S-EPMC7494901 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature