Straightforward and Controlled Synthesis of Porphyrin-Phthalocyanine-Porphyrin Heteroleptic Triple-Decker Assemblies.

ABSTRACT: A versatile and straightforward protocol is disclosed for controlled synthesis of complex lanthanide-bridged heteroleptic porphyrin-phthalocyanine triple-decker assemblies. Two porphyrins, linked by a flexible spacer chain of intermediate length, sequentially capture lanthanide ions and a phthalocyanine to efficiently form the triple-decker complex. The bridge directs assembly, but also controls the mobility of the central macrocycle and further imparts a fully eclipsed arrangement of all three rings.

SUBMITTER: Gonzalez-Lucas D 

PROVIDER: S-EPMC7497087 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature