Selective oxo ligand functionalisation and substitution reactivity in an oxo/catecholate-bridged U^IV/U^IV Pacman complex.

ABSTRACT: The oxo- and catecholate-bridged U^IV/U^IV Pacman complex [{(py)U^IVOU^IV(μ-O₂C₆H₄)(py)}(L^A)] A (L^A = a macrocyclic "Pacman" ligand; anthracenylene hinge between N₄-donor pockets, ethyl substituents on meso-carbon atom of each N₄-donor pocket) featuring a bent U^IV-O-U^IV oxo bridge readily reacts with small molecule substrates to undergo either oxo-atom functionalisation or substitution. Complex A reacts with H₂O or MeOH to afford [{(py)U^IV(μ-OH)₂U^IV(μ-O₂C₆H₄)(py)}(L^A)] (1) and [{(py)U^IV(μ-OH)(μ-OMe)U^IV(μ-O₂

SUBMITTER: Cowie BE 

PROVIDER: S-EPMC7499863 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature