Charge Redistribution Caused by S,P Synergistically Active Ru Endows an Ultrahigh Hydrogen Evolution Activity of S-Doped RuP Embedded in N,P,S-Doped Carbon.

ABSTRACT: Water splitting for production of hydrogen as a clean energy alternative to fossil fuel has received much attention, but it is still a tough challenge to synthesize electrocatalysts with controllable bonding and charge distribution. In this work, ultrafine S-doped RuP nanoparticles homogeneously embedded in a N, P, and S-codoped carbon sheet (S-RuP@NPSC) is synthesized by pyrolysis of poly(cyclotriphosphazene-co-4,4'-sulfonyldiphenol) (PZS) as the source of C/N/S/P. The bondings between Ru and N, P, S in PZS are regulated to synthesize RuS₂ (800 °C) and S-RuP (900 °C) by different calcination temperatures. The S-RuP@NPSC with low Ru loading of 0.8 wt% with abundant active catalytic sites possesses high utilization of Ru, the mass catalytic activity is 22.88 times than 20

SUBMITTER: Liu X 

PROVIDER: S-EPMC7507474 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature