In situ tuning of electronic structure of catalysts using controllable hydrogen spillover for enhanced selectivity.

ABSTRACT: In situ tuning of the electronic structure of active sites is a long-standing challenge. Herein, we propose a strategy by controlling the hydrogen spillover distance to in situ tune the electronic structure. The strategy is demonstrated to be feasible with the assistance of CoO_x/Al₂O₃/Pt catalysts prepared by atomic layer deposition in which CoO_x and Pt nanoparticles are separated by hollow Al₂O₃ nanotubes. The strength of hydrogen spillover from Pt to CoO_x can be precisely tailored by varying the Al₂O₃ thickness. Using CoO_x/Al₂O₃ catalyzed styrene epoxidation as an example, the CoO_x/Al₂O₃/Pt with 7 nm Al₂O₃

SUBMITTER: Xiong M 

PROVIDER: S-EPMC7508871 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature