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Rapid and Low-Temperature Molecular Precursor Approach toward Ternary Layered Metal Chalcogenides and Oxides: Mo_1-x W _x S₂ and Mo_1-x W _x O₃ Alloys (0 ≤ x ≤ 1).

ABSTRACT: Metal sulfide and metal oxide alloys of the form Mo_1-x W _x S₂ and Mo_1-x W _x O₃ (0 ≤ x ≤ 1) are synthesized with varying nominal stoichiometries (x = 0, 0.25, 0.50, 0.75, and 1.0) by thermolysis of the molecular precursors MoL₄ and WS(S₂)L₂ (where L = S₂CNEt₂) in tandem and in various ratios. Either transition-metal dichalcogenides or transition-metal oxides can be produced from the same pair of precursors by the choice of reaction conditions; metal sulfide alloys of the form Mo_1-x W _x S₂ are produced in an argon atmosphere, while the corresponding metal oxide alloys Mo_1-x

SUBMITTER: Zeng N

PROVIDER: S-EPMC7513577 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature

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Rapid and Low-Temperature Molecular Precursor Approach toward Ternary Layered Metal Chalcogenides and Oxides: Mo_1-x W _x S₂ and Mo_1-x W _x O₃ Alloys (0 ≤ x ≤ 1).

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Rapid and Low-Temperature Molecular Precursor Approach toward Ternary Layered Metal Chalcogenides and Oxides: Mo1-x W x S2 and Mo1-x W x O3 Alloys (0 ≤ x ≤ 1).

OmicsDI is part of the ELIXIR infrastructure

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Rapid and Low-Temperature Molecular Precursor Approach toward Ternary Layered Metal Chalcogenides and Oxides: Mo_1-x W _x S₂ and Mo_1-x W _x O₃ Alloys (0 ≤ x ≤ 1).