Sinter-Resistant Nanoparticle Catalysts Achieved by 2D Boron Nitride-Based Strong Metal-Support Interactions: A New Twist on an Old Story.

ABSTRACT: Strong metal-support interaction (SMSI) is recognized as a pivotal strategy in hetereogeneous catalysis to prevent the sintering of metal nanoparticles (NPs), but issues including restriction of supports to reducible metal oxides, nonporous architecture, sintering by thermal treatment at >800 °C, and unstable nature limit their practical application. Herein, the construction of non-oxide-derived SMSI nanocatalysts based on highly crystalline and nanoporous hexagonal boron nitride (h-BN) 2D materials was demonstrated via in situ encapsulation and reduction using NaBH₄, NaNH₂, and noble metal salts as precursors. The as-prepared nanocatalysts exhibited robust thermal stability and sintering resistance to withstand thermal treatment at up to 950 °C, rendering them with h

SUBMITTER: Chen H 

PROVIDER: S-EPMC7517410 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature