Regio- and Stereoselective Rhodium(II)-Catalyzed C-H Functionalization of Organosilanes by Donor/Acceptor Carbenes Derived from Aryldiazoacetates.

ABSTRACT: The regioselective and enantioselective intermolecular sp³ C-H functionalization of silicon-substituted alkanes with aryl diazoacetates was accomplished using the recently developed dirhodium catalyst Rh₂( S-TPPTTL)₄. These reactions generate a diverse array of stereodefined substituted silacycloalkanes with high enantioselectivity and diastereoselectivity.

SUBMITTER: Garlets ZJ 

PROVIDER: S-EPMC7526748 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature