Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Spinach-Derived Porous Carbon Nanosheets as High-Performance Catalysts for Oxygen Reduction Reaction.

ABSTRACT: Biomass-derived porous carbon materials are effective electrocatalysts for oxygen reduction reaction (ORR), with promising applications in low-temperature fuel cells and metal-air batteries. Herein, we developed a synthesis procedure that used spinach as a source of carbon, iron, and nitrogen for preparing porous carbon nanosheets and studied their ORR catalytic performance. These carbon sheets showed a very high ORR activity with a half-wave potential of +0.88 V in 0.1 M KOH, which is 20 mV more positive than that of commercial Pt/C catalysts. In addition, they showed a much better long-term stability than Pt/C and were insensitive to methanol. The remarkable ORR performance was attributed to the accessible high-density active sites that are primarily from Fe-N _x moieties. This work paves the way toward the use of metal-enriching plants as a source for preparing porous carbon materials for electrochemical energy conversion and storage applications.

SUBMITTER: Liu X

PROVIDER: S-EPMC7528166 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Spinach-Derived Porous Carbon Nanosheets as High-Performance Catalysts for Oxygen Reduction Reaction.

Liu Xiaojun X Culhane Casey C Li Wenyue W Zou Shouzhong S

ACS omega 20200915 38

Biomass-derived porous carbon materials are effective electrocatalysts for oxygen reduction reaction (ORR), with promising applications in low-temperature fuel cells and metal-air batteries. Herein, we developed a synthesis procedure that used spinach as a source of carbon, iron, and nitrogen for preparing porous carbon nanosheets and studied their ORR catalytic performance. These carbon sheets showed a very high ORR activity with a half-wave potential of +0.88 V in 0.1 M KOH, which is 20 mV mor ...[more]

PMID: 33015453

Similar Datasets

Hierarchical Porous Carbon-PtPd Catalysts and Their Activity toward Oxygen Reduction Reaction.

Project description:PtPd bimetallic catalysts supported on hierarchical porous carbon (HPC) with different porous sizes were developed for the oxygen reduction reaction (ORR) toward fuel cell applications. The HPC pore size was controlled by using SiO2 nanoparticles as a template with different sizes, 287, 371, and 425 nm, to obtain three HPC materials denoted as HPC-1, HPC-2, and HPC-3, respectively. PtPd/HPC catalysts were characterized by scanning electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, and high-resolution transmission electron microscopy. The electrochemical performance was examined by cyclic voltammetry and linear sweep voltammetry. PtPd/HPC-2 turned out to be the most optimal catalyst with an electroactive surface area (ESA) of 40.2 m2 g-1 and a current density for ORR of -1285 A g-1 at 2 mV s-1 and 1600 rpm. In addition, we conducted a density functional theory computational study to examine the interactions between a PtPd cluster and a graphitic domain of HPC, as well as the interaction between the catalyst and the oxygen molecule. These results reveal the strong influence of the porous size (in HPC) and ESA values (in PtPd nanoparticles) in the mass transport process which rules the electrochemical performance.

| S-EPMC9219087 | biostudies-literature

Porous Carbon Networks Derived From Graphitic Carbon Nitride for Efficient Oxygen Reduction Reaction.

Project description:Great efforts have been dedicated to finding economic and efficient oxygen reduction reaction (ORR) for fuel cell technology. Among various catalysts, N-doped carbon-based nanomaterials have attracted much attention due to low-cost, noble metal free, and good durability. Herein, we developed a facile and economic strategy to prepare nitrogen-doped carbon networks for efficient ORR application. The g-C3N4 is used as the template and N source, and dopamine is used as the carbon source. By simple hydrothermal treatment and sintering, N-doped carbon network structures with high specific surface area, effective ORR activity, and superior durability could be acquired. The present strategy is free of involving generally multistep, poisonous reagents, and complication of removing template for fabrication of 3D carbon structures.

| S-EPMC6656852 | biostudies-literature

Biomass Juncus Derived Nitrogen-Doped Porous Carbon Materials for Supercapacitor and Oxygen Reduction Reaction.

Project description:Juncus is a perennial herb aquatic plant found worldwide, with high reproductive ability in warm regions. It has three-dimensional hierarchical porous triangular networks structures composited of tubular fibers. Here, juncus derived nitrogen-doped porous carbon (NDPC) was prepared by mixing juncus and ZnCl2 through one-step pyrolysis and activation which is a low-cost, simple, and environmentally friendly method. The NDPC had hierarchical porous structures and a high specific surface area and was applied for supercapacitor and oxygen reduction reaction (ORR). The resulted NDPC-3-800 was prepared by mixing juncus with ZnCl2 at a mass ratio of 1:3 and then carbonized at 800°C, it was used as electrode material of a supercapacitor. The supercapacitor exhibited excellent specific capacitance of 290.5 F g-1 and 175.0 F g-1 in alkaline electrolyte at the current densities of 0.5 A g-1 and 50 A g-1, respectively. The supercapacitor showed good cycle stability, and the capacitance was maintained at 94.5% after 10,000 cycles. The NDPC-5-800 was prepared by mixing juncus with ZnCl2 at a mass ratio of 1:5 and then carbonized at 800°C. It exhibited outstanding ORR catalytic activity and stability attributing to their high specific surface area and abundant actives sites. The juncus can derive various materials for application in different fields.

| S-EPMC7174754 | biostudies-literature

Cobalt/nitrogen codoped carbon nanosheets derived from catkins as a high performance non-noble metal electrocatalyst for oxygen reduction reaction and hydrogen evolution reaction.

Project description:Novel energy devices which are capable of alleviating and/or solving the energy dilemma such as overall water splitting and fuel cells require the development of highly efficient catalysts, especially cheap high performance non-precious metal (NPM) catalysts. Here, we prepare highly efficient NPM catalysts of cobalt and nitrogen codoped carbon nanosheets (Co/N-CNSs) for oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER) using harmful environment-polluting waste of biomass catkins as carbon precursors via a mild mechanical exfoliation and chemical process which is facile, low-cost, environmentally friendly and up-scalable. Compared with a commercial platinum-based catalyst (commercial 20% Pt/C), the Co/N-CNS electrocatalysts show outstanding ORR activity, acceptable HER activity and long term stability with an onset potential of 0.92 V versus the reversible hydrogen electrode (vs. RHE) and a half-wave potential of 0.83 V vs. the RHE in alkaline electrolytes. The excellent performance is closely related to the presence of abundant CoN x active sites. This work offers a novel and effective approach for preparing highly efficient ORR and HER NPM electrocatalysts from waste biomass materials.

| S-EPMC9058186 | biostudies-literature

Polyaniline-Derived N-Doped Ordered Mesoporous Carbon Thin Films: Efficient Catalysts towards Oxygen Reduction Reaction.

Project description:One of the most challenging targets in oxygen reduction reaction (ORR) electrocatalysts based on N-doped carbon materials is the control of the pore structure and obtaining nanostructured thin films that can easily be incorporated on the current collector. The carbonization of nitrogen-containing polymers and the heat treatment of a mixture of carbon materials and nitrogen precursor are the most common methods for obtaining N-doped carbon materials. However, in this synthetic protocols, the surface area and pore distribution are not controlled. This work enables the preparation of 2D-ordered N-doped carbon materials through the carbonization of 2D polyaniline. For that purpose, aniline has been electropolymerized within the porous structure of two different templates (ordered mesoporous Silica and ordered mesoporous Titania thin films). Thus, aniline has been impregnated into the porous structure and subsequently electropolymerized by means of chronoamperometry at constant potential. The resultant samples were heat-treated at 900 °C with the aim of obtaining 2D N-doped carbon materials within the template structures. Polyaniline and polyaniline-derived carbon materials have been analyzed via XPS and TEM and characterized by electrochemical measurements. It is worth noting that the obtained 2D-ordered mesoporous N-doped carbon materials have proved to be highly active electrocatalysts for the ORR because of the formation of quaternary nitrogen species during the heat treatment.

| S-EPMC7602833 | biostudies-literature

High Performance Heteroatoms Quaternary-doped Carbon Catalysts Derived from Shewanella Bacteria for Oxygen Reduction.

Project description:A novel heteroatoms (N, P, S and Fe) quaternary-doped carbon (HQDC-X, X refers to the pyrolysis temperature) can be fabricated by directly pyrolyzing a gram-negative bacteria, S. oneidensis MR-1 as precursors at 800 °C, 900 °C and 1000 °C under argon atmosphere. These HQDC-X catalysts maintain the cylindrical shape of bacteria after pyrolysis under high temperatures, while heteroatoms including N, P, S and Fe distribute homogeneously on the carbon frameworks. As a result, HQDC-X catalysts exhibit excellent electrocatalytic activity for ORR via a dominant four-electron oxygen reduction pathway in alkaline medium, which is comparable with that of commercial Pt/C. More importantly, HQDC-X catalysts show better tolerance for methanol crossover and CO poisoning effects, long-term durability than commercial Pt/C, which could be promising alternatives to costly Pt-based electrocatalysts for ORR. The method may provide a promising avenue to develop cheap ORR catalysts from inexpensive, scalable and biological recursors.

| S-EPMC4658503 | biostudies-literature

Diatomite waste derived N-doped porous carbon for applications in the oxygen reduction reaction and supercapacitors.

Project description:Biomass waste recycling and utilization is of great significance for improving ecological environments and relieving the current energy crisis. Waste diatomite with an adsorbed mass of yeast protein resulting from beer filtration is feasibly converted into N-doped porous carbon (NPC) via high temperature thermal treatment. The resulting NPC inherits the three-dimensional hierarchical structure of the diatomite, with a unique rich-pore feature composed of micro/meso/macropores, which is beneficial for high exposure of the electrocatalytic sites and ion transfer and diffusion. The NPC compounds with controllable nitrogen doping are used for the oxygen reduction reaction (ORR) and in a supercapacitor. NPC-2 exhibits a half-wave potential of 0.801 V comparable to that (0.812 V) of commercially available Pt/C in alkaline media, along with a good methanol tolerance capacity and long-term stability for the ORR. Furthermore, as an electrode material, a symmetric supercapacitor based on NPC-2 manifests an outstanding specific capacitance of 151.5 F g-1 at a current density of 1 A g-1 and a considerable capacitance retention of 90.5% after a cycling performance test of 10 000 cycles. The NPC-2 based symmetric SC delivered an energy density of 13.47 W h kg-1 at a power density of 400 W kg-1. This work highlights the environmental significance of converting waste diatomite into metal-free ORR catalysts and electrode materials for energy conversion and storage technologies.

| S-EPMC9419853 | biostudies-literature

Electrochemical Performance of Metal-Free Carbon-Based Catalysts from Different Hydrothermal Carbonization Treatments for Oxygen Reduction Reaction.

Project description:This research investigates the difference between products obtained through two hydrothermal carbonization treatments. Our aim is to synthesize metal-free, carbon-based catalysts for the oxygen reduction reaction (ORR) to serve as efficient and cost-effective alternatives to platinum-based catalysts. Catalysts synthesized using the traditional hydrothermal approach exhibit a higher electrocatalytic activity for ORR in alkaline media, despite their more energy-intensive production process. The superior performance is attributed to differences in the particle morphology and the chemical composition of the particle surfaces. The presence of functional groups on the surfaces of catalysts obtained via a traditional approach significantly enhances ORR activity by facilitating deprotonation reactions in an alkaline environment. Our research aims to provide a reference for future investigations, shifting the focus to the fine-tuning of surface chemical compositions and morphologies of metal-free catalysts to enhance ORR activity.

| S-EPMC10820196 | biostudies-literature

Porous Organic Polymer-Derived Carbon Composite as a Bimodal Catalyst for Oxygen Evolution Reaction and Nitrophenol Reduction.

Project description:Ethylene diamine-based porous organic polymer (EPOP) was synthesized, carbonized at different temperatures, and characterized. The successful formation of the triazine polymer was confirmed by Fourier-transform infrared spectroscopy, 13C, and 15N cross-polarization magic angle spinning solid-state NMR. The two-dimensional layered architecture and graphitic nature of the samples resembled that of nitrogen-doped amorphous carbon, as confirmed by Raman, powder X-ray diffraction, and transmission electron microscopy measurements. The catalytic activity of these materials toward nitrophenol reduction and electrocatalytic activity toward oxygen evolution reaction (OER) were systematically evaluated in detail. Electrocatalytic activity toward oxygen evolution reaction was systematically evaluated by chronoamperometry and linear sweep voltammetry. Results clearly demonstrate that all of these catalysts exhibit good OER activity and excellent stability. Among all catalysts, EPOP-700 showed better OER activity, as reflected by its onset potential and current density, comparable with that of the metal-based OER catalysts and better than that of metal-free catalysts. Further, their catalytic activity toward the reduction of 4-nitrophenol to 4-aminophenol was tested with NaBH4; although all of these catalysts showed good catalytic activity; EPOP-800 displayed better catalytic activity.

| S-EPMC6644422 | biostudies-literature

Nitrogen-Doped Carbon Nanosheets Decorated With Mn2O3 Nanoparticles for Excellent Oxygen Reduction Reaction.

Project description:The purpose of this study is to develop an active, low cost, non-precious, stable, and high-performance catalyst for oxygen reduction reaction (ORR). In this regard, Mn2O3-decorated nitrogen-doped carbon nanosheets (Mn2O3/NC) are fabricated by a two-step strategy involving a hydrothermal method and a solid-state method. In the resultant structures, very fine Mn2O3 nanoparticles with an average size of about 5 nm are strongly attached to nitrogen-doped carbon nanosheets. The role of the Mn2O3 nanoparticles is to provide active sites for ORR, while the presence of the nitrogen-doped carbon not only enhances the conductivity of the overall structure but is also helpful for overall stability. The Mn2O3/NC shows good onset potential (0.80 V@-1 mA/cm2), methanol crossover effect, and stability (90%).

| S-EPMC6856643 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data