Comparative Catalytic Properties of Supported and Encapsulated Gold Nanoparticles in Homocoupling Reactions.

ABSTRACT: This report describes strategies to increase the reactive surfaces of integrated gold nanoparticles (AuNPs) by employing two different types of host materials that do not possess strong electrostatic and/or covalent interactive forces. These composite particles are then utilized as highly reactive and recyclable quasi-homogeneous catalysts in a C-C bond forming reaction. The use of mesoporous TiO₂ and poly(N-isopropylacrylamide), PNIPAM, particles allows for the formation of relatively small and large guest AuNPs and provides the greatly improved stability of the resulting composite particles. As these AuNPs are physically incorporated into the mesoporous TiO₂ (i.e., supported AuNPs) and PNIPAM particles (i.e., encapsulated AuNPs), their surfaces are maximized to serv

SUBMITTER: Jang W 

PROVIDER: S-EPMC7533535 | biostudies-literature | 2020

REPOSITORIES: biostudies-literature