Crystal structure of bis-{μ-2-[bis-(2-hy-droxy-eth-yl)amino]-ethano-lato}bis-(μ-3,5-di-methyl-pyrazolato)tricopper(II) dibromide sesquihydrate.

ABSTRACT: In the title bicyclic trinuclear pyrazolate amino-alcohol complex, [Cu₃(C₅H₇N₂)₂(C₆H₁₄NO₃)₂]Br₂·1.5H₂O, the central Cu atom lies on a center of symmetry and is involved in the formation of two five-membered rings. It has a coordination number of 4, is in a distorted tetra-hedral environment and is connected by the bridging oxygen atoms of the deprotonated OH groups of different amino-alcohol groups, and by the N atoms of deprotonated di-methyl-pyrazole ligands. The peripheral Cu atom is in a trigonal-bipyramidal coordination environment formed by the nitro-gen atom of the deprotonated bridging di-methyl-pyrazole unit, the bridging oxygen atom of the deprotonated OH group

SUBMITTER: Vynohradov OS 

PROVIDER: S-EPMC7534225 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature