1,3-Di-naphthalimide Conjugate of Calix[4]arene as a Sensitive and Selective Sensor for Trinitrophenol and This Turns Reversible when Hybridized with Carrageenan as Beads.

ABSTRACT: A fluorescent naphthalimide conjugate of calix[4]arene (L₁ ) has been synthesized and characterized. The selective and efficient detection of trinitrophenol (TNP) by L₁ among nine other different nitroaromatic compounds was demonstrated using absorption and fluorescence spectroscopy. The minimum detection limit is 29 nM, which is the lowest reported so far by any conjugate of calixarene toward TNP. The fluorescence quenching is associated with a high Stern-Volmer constant of 3.3 ± 0.4 × 10⁵ M^-1. The scanning electron microscopy (SEM) and transmission electron microscopy (TEM) data revealed a network structure with pores having a weighted average size of 0.66 ± 0.08 μm for L₁ . When incubated with TNP, the pores wer

SUBMITTER: Narula A 

PROVIDER: S-EPMC7557251 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature