Electrocatalytic Properties of 3D Hierarchical Graphitic Carbon-Cobalt Nanoparticles for Urea Oxidation.

ABSTRACT: A 3D hierarchical graphitic carbon nanostructure encapsulating cobalt(0)/cobalt oxide nanoparticles (CoGC) has been prepared by solid-state pyrolysis of a mixture of anthracene and cobalt 2,2'-bipyridine terephthalate complex at 850 °C. Based on the Brunauer-Emmett-Teller (BET) and Barrett-Joyner-Halenda (BJH) methods, the prepared material has high surface area (186.8 m² g^-1) with an average pore width of 205.5 Å. XPS reveals the functionalization of carbon with different oxygen-containing groups, such as carboxylic acid groups. The presence of metallic cobalt nanoparticles with cubic and hexagonal crystalline structures encapsulated in graphitized carbon is confirmed using XRD and TEM. Raman spectroscopy indicates a graphitization degree of I _D/

SUBMITTER: Alotaibi N 

PROVIDER: S-EPMC7558028 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature