Heteronuclear Dirhodium-Gold Anionic Complexes: Polymeric Chains and Discrete Units.

ABSTRACT: In this article, we report on the synthesis and characterization of the tetracarboxylatodirhodium(II) complexes [Rh2(μ-O2CCH2OMe)4(THF)2] (1) and [Rh2(μ-O2CC6H4-p-CMe3)4(OH2)2] (2) by metathesis reaction of [Rh2(μ-O2CMe)4] with the corresponding ligand acting also as the reaction solvent. The reaction of the corresponding tetracarboxylato precursor, [Rh2(μ-O2CR)4], with PPh4[Au(CN)2] at room temperature, yielded the one-dimensional polymers (PPh4)n[Rh2(μ-O2CR)4Au(CN)2]n (R = Me (3), CH2OMe (4), CH2OEt (5)) and the non-polymeric compounds (PPh4)2{Rh2(μ-O2CR)4[Au(CN)2]2} (R = CMe3 (6), C6H4-p-CMe3 (7)). The structural characterization of 1, 3·2CH2Cl2, 4·3CH2Cl2, 5, 6, and 7·2OCMe2 is also provided with a detailed description of their crystal structures and intermolecular interactions. The po

SUBMITTER: Fernandez-Bartolome E 

PROVIDER: S-EPMC7563758 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature