Enhancement of Energy Transfer Efficiency with Structural Control of Multichromophore Light-Harvesting Assembly.

ABSTRACT: Multichromophore systems (MCSs) are envisioned as building blocks of molecular optoelectronic devices. While it is important to understand the characteristics of energy transfer in MCSs, the effect of multiple donors on energy transfer has not been understood completely, mainly due to the lack of a platform to investigate such an effect systematically. Here, a systematic study on how the number of donors (n _D) and interchromophore distances affect the efficiency of energy transfer (η _FRET) is presented. Specifically, η _FRET is calculated for a series of model MCSs using simulations, a series of multiporphyrin dendrimers with systematic variation of n _D and interdonor distances is synthesized, and η _FRET

SUBMITTER: Oh I 

PROVIDER: S-EPMC7578888 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature