Facile H/D Exchange at (Hetero)Aromatic Hydrocarbons Catalyzed by a Stable Trans-Dihydride N-Heterocyclic Carbene (NHC) Iron Complex.

ABSTRACT: Earth-abundant metal pincer complexes have played an important role in homogeneous catalysis during the last ten years. Yet, despite intense research efforts, the synthesis of iron PC_carbeneP pincer complexes has so far remained elusive. Here we report the synthesis of the first PC_NHCP functionalized iron complex [(PC_NHCP)FeCl₂] (1) and the reactivity of the corresponding trans-dihydride iron(II) dinitrogen complex [(PC_NHCP)Fe(H)₂N₂)] (2). Complex 2 is stable under an atmosphere of N₂ and is highly active for hydrogen isotope exchange at (hetero)aromatic hydrocarbons under mild conditions (50 °C, N₂). With benzene-d₆ as the deuterium source, easil

SUBMITTER: Garhwal S 

PROVIDER: S-EPMC7586338 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature