Engineering active sites on hierarchical transition bimetal oxides/sulfides heterostructure array enabling robust overall water splitting.

ABSTRACT: Rational design of the catalysts is impressive for sustainable energy conversion. However, there is a grand challenge to engineer active sites at the interface. Herein, hierarchical transition bimetal oxides/sulfides heterostructure arrays interacting two-dimensional MoO_x/MoS₂ nanosheets attached to one-dimensional NiO_x/Ni₃S₂ nanorods were fabricated by oxidation/hydrogenation-induced surface reconfiguration strategy. The NiMoO_x/NiMoS heterostructure array exhibits the overpotentials of 38 mV for hydrogen evolution and 186 mV for oxygen evolution at 10 mA cm^-2, even surviving at a large current density of 500 mA cm^-2 with long-term stability. Due to optimized adsorption energies and accelerated water sp

SUBMITTER: Zhai P 

PROVIDER: S-EPMC7596725 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature