Luminescent Colloidal InSb Quantum Dots from In Situ Generated Single-Source Precursor.

ABSTRACT: Despite recent advances, the synthesis of colloidal InSb quantum dots (QDs) remains underdeveloped, mostly due to the lack of suitable precursors. In this work, we use Lewis acid-base interactions between Sb(III) and In(III) species formed at room temperature in situ from commercially available compounds (viz., InCl₃, Sb[NMe₂]₃ and a primary alkylamine) to obtain InSb adduct complexes. These complexes are successfully used as precursors for the synthesis of colloidal InSb QDs ranging from 2.8 to 18.2 nm in diameter by fast coreduction at sufficiently high temperatures (≥230 °C). Our findings allow us to propose a formation mechanism for the QDs synthesized in our work, which is based on a nonclassical nucleation event, followed by aggregative

SUBMITTER: Busatto S 

PROVIDER: S-EPMC7596776 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature