Highly Efficient Additive-Free Dehydrogenation of Neat Formic Acid.

ABSTRACT: Formic acid (FA) is a promising hydrogen carrier which can play an instrumental role in the overall implementation of a hydrogen economy. In this regard, it is important to generate H₂ gas from neat FA without any solvent/additive, for which existing systems are scarce. Here we report the remarkable catalytic activity of a ruthenium 9H-acridine pincer complex for this process. The catalyst is unusually stable and robust in FA even at high temperatures and can catalyse neat FA dehydrogenation for over a month, with a total turnover number of 1,701,150, while also generating high H₂/CO₂ gas pressures (tested up to 100 bars). Mechanistic investigations and DFT studies are conducted to fully understand the molecular mechanism to the process. Overall, the high a

SUBMITTER: Kar S 

PROVIDER: S-EPMC7614505 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature