Electrolysis-assisted UV/sulfite oxidation for water treatment with automatic adjustments of solution pH and dissolved oxygen.

ABSTRACT: Sulfite as precursor to generate sulfate radical (SO₄ ^•-) for water treatment has gained attention. Here we report a metal-free and highly efficient electro/UV/sulfite process to produce SO₄ ^•- for water treatment. UV/sulfite reaction induces sulfite radical (SO₃ ^•-), which transforms into SO₄ ^•- in the presence of oxygen generated by water electrolysis. Electro/UV/sulfite process generates a steady-state SO₄ ^•- concentration of 0.2 to 1.1 × 10^-12 M in our tests. Solution pH affects sulfite species distribution, and higher pH mediates improved yield of steady-state SO₄ ^•- concentration. Effect of sulfite concentration exhibits a bell-shaped pattern

SUBMITTER: Chen L 

PROVIDER: S-EPMC7641513 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature