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Crystal structure of the unusual coordination polymer catena-poly[[gold(I)-μ-1,2-bis-(di-phenyl-phosphino-thio-yl)ethane-κ² S:S'] di-bromido-aurate(I)].

ABSTRACT: In the title compound, {[Au(C₂₆H₂₄P₂S₂)][AuBr₂]} _n , the gold(I) centres of the cation are coordinated by the P=S groups of the di-sulfide ligands to form a chain polymer parallel to the c axis. Both independent gold atoms lie on the same twofold axis, and the midpoint of the H₂C-CH₂ bond lies on an inversion centre. The anions flank the polymeric chain; they are connected to it by short aurophilic inter-actions and C-H⋯Br contacts, and to each other by Br⋯Br contacts.

SUBMITTER: Taouss C

PROVIDER: S-EPMC7643243 | biostudies-literature | 2020 Nov

REPOSITORIES: biostudies-literature

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Crystal structure of the unusual coordination polymer catena-poly[[gold(I)-μ-1,2-bis-(di-phenyl-phosphino-thio-yl)ethane-κ² S:S'] di-bromido-aurate(I)].

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Dataset Information

Crystal structure of the unusual coordination polymer catena-poly[[gold(I)-μ-1,2-bis-(di-phenyl-phosphino-thio-yl)ethane-κ2 S:S'] di-bromido-aurate(I)].

OmicsDI is part of the ELIXIR infrastructure

Tweets

Crystal structure of the unusual coordination polymer catena-poly[[gold(I)-μ-1,2-bis-(di-phenyl-phosphino-thio-yl)ethane-κ² S:S'] di-bromido-aurate(I)].