Magnetism, Conductivity and Spin-Spin Interactions in Layered Hybrid Structure of Anionic Radicals [Ni(dmit)₂] Alternated by Iron(III) Spin-Crossover Complex [Fe(III)(3-OMe-Sal₂trien)] and Ferric Moiety Precursors.

ABSTRACT: In this study, crystals of the hybrid layered structure, combined with Fe(III) Spin-Crossover (SCO) complexes with metal-dithiolate anionic radicals, and the precursors with nitrate and iodine counterions, are obtained and characterized. [Fe(III)(3-OMe-Sal₂trien)][Ni(dmit)₂] (1), [Fe(III)(3-OMe-Sal₂trien)]NO₃·H₂O (2), [Fe(III)(3-OMe-Sal₂trien)]I (3) (3-OMe-Sal₂trien = hexadentate N₄O₂ Schiff base is the product of the condensation of triethylenetetramine with 3-methoxysalicylaldehyde; H₂dmit = 2-thioxo-1,3-dithiole-4,5-dithiol). Bulk SCO transition was not achieved in the range 2.0-350 K for all three compounds. Alternatively, the hybrid system (1) exhib

SUBMITTER: Shvachko YN 

PROVIDER: S-EPMC7663777 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature