Three-Dimensionally Ordered Macroporous ZnO Framework as Dual-Functional Sulfur Host for High-Efficiency Lithium-Sulfur Batteries.

ABSTRACT: A three-dimensionally ordered macroporous ZnO (3DOM ZnO) framework was synthesized by a template method to serve as a sulfur host for lithium-sulfur batteries. The unique 3DOM structure along with an increased active surface area promotes faster and better electrolyte penetration accelerating ion/mass transfer. Moreover, ZnO as a polar metal oxide has a strong adsorption capacity for polysulfides, which makes the 3DOM ZnO framework an ideal immobilization agent and catalyst to inhibit the polysulfides shuttle effect and promote the redox reactions kinetics. As a result of the stated advantages, the S/3DOM ZnO composite delivered a high initial capacity of 1110 mAh g^-1 and maintained a capacity of 991 mAh g^-1 after 100 cycles at 0.2 C as a cathode in a lithium-sulfur b

SUBMITTER: Han H 

PROVIDER: S-EPMC7697050 | biostudies-literature | 2020 Nov

REPOSITORIES: biostudies-literature