Intermolecular Hydroaminoalkylation of Propadiene.

ABSTRACT: Intermolecular hydroaminoalkylation reactions of propadiene with selected secondary amines take place in the presence of a 2,6-bis(phenylamino)pyridinato titanium catalyst. The corresponding products, synthetically useful allylamines, are formed in convincing yields and with high selectivities. In addition, propadiene easily inserts into the titanium-carbon bond of a titanaaziridine.

SUBMITTER: Kaper T 

PROVIDER: S-EPMC7702142 | biostudies-literature | 2020 Nov

REPOSITORIES: biostudies-literature