Underpotential lithium plating on graphite anodes caused by temperature heterogeneity.

ABSTRACT: Rechargeability and operational safety of commercial lithium (Li)-ion batteries demand further improvement. Plating of metallic Li on graphite anodes is a critical reason for Li-ion battery capacity decay and short circuit. It is generally believed that Li plating is caused by the slow kinetics of graphite intercalation, but in this paper, we demonstrate that thermodynamics also serves a crucial role. We show that a nonuniform temperature distribution within the battery can make local plating of Li above 0 V vs. Li⁰/Li⁺ (room temperature) thermodynamically favorable. This phenomenon is caused by temperature-dependent shifts of the equilibrium potential of Li⁰/Li⁺ Supported by simulation results, we confirm the likelihood of this failure mechanism

SUBMITTER: Wang H 

PROVIDER: S-EPMC7703581 | biostudies-literature | 2020 Nov

REPOSITORIES: biostudies-literature