Oxovanadium(IV) and Nickel(II) complexes obtained from 2,2'-dihydroxybenzophenone-S-methyl-thiosemicarbazone: Synthesis, characterization, electrochemistry, and antioxidant capability.

ABSTRACT: 2,2'-Dihydroxybenzophenone-S-methyl-thiosemicarbazone and 3-methoxy-salicylaldehyde were reacted in the presence of oxovanadium(IV) or nickel(II) ions to yield the N₂O₂-type-chelate complex. The synthesized complexes were characterized by employing elemental analysis, electronic and infrared spectra, ¹H NMR spectra, magnetic measurements, and thermogravimetric analyses. The expected structures of oxovanadium(IV) and nickel(II) complexes were confirmed by using the single-crystal X-ray diffraction method. The presence of π-π stacked dimeric structures provided stronger crystalline formations. The optimized geometries and vibrational frequencies of the compounds were obtained using the DFT/ωB97XD method with the 6-31G (d,p) basis set and compared with the exp

SUBMITTER: Ilhan-Ceylan B 

PROVIDER: S-EPMC7724315 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature